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15 pages, 3434 KiB  
Article
Underwater Explosion Analysis on Composite Marine Structures: A Comparison Between CEL and UEL Methods
by Jacopo Bardiani, Giada Kyaw Oo D’Amore, Claudio Sbarufatti and Andrea Manes
J. Compos. Sci. 2025, 9(4), 177; https://doi.org/10.3390/jcs9040177 (registering DOI) - 5 Apr 2025
Viewed by 17
Abstract
Underwater explosion (UNDEX) problems are typically simulated using numerical coupled techniques, such as the Coupled Eulerian–Lagrangian (CEL) method, to accurately capture fluid–structure interaction (FSI) effects, which are non-negligible in such scenarios. While highly accurate, coupled methods are computationally expensive. Alternatively, uncoupled (or decoupled) [...] Read more.
Underwater explosion (UNDEX) problems are typically simulated using numerical coupled techniques, such as the Coupled Eulerian–Lagrangian (CEL) method, to accurately capture fluid–structure interaction (FSI) effects, which are non-negligible in such scenarios. While highly accurate, coupled methods are computationally expensive. Alternatively, uncoupled (or decoupled) techniques, like the Uncoupled Eulerian–Lagrangian (UEL) approach, offer greater computational efficiency by neglecting FSI effects, but at the cost of reduced predictive accuracy. This study provides a qualitative and quantitative evaluation of how far UEL results deviate from the more realistic CEL solutions in UNDEX scenarios. The comparison focuses on the structural response of a floating double-bottom fiber-reinforced composite structure subject to a near-field UNDEX. The numerical results indicate that the UEL approach overestimates structural response by up to 190% compared to CEL when added mass effects are considered, and up to 400% when they are not. However, a correction strategy based on modifying the Hull Shock Factor (HSF) is proposed to bridge the gap between UEL and CEL predictions. This study demonstrates that, with proper calibration, UEL simulations can serve as a computationally efficient alternative for preliminary UNDEX assessments in naval engineering. Full article
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30 pages, 7078 KiB  
Article
Enhancement of Mechanical and Tribological Properties of MWCNT-Reinforced Bio-Based Epoxy Composites Through Optimization and Molecular Dynamics Simulation
by Pavan Hiremath, Y. M. Shivaprakash, Kiran Keshyagol, Suhas Kowshik, B. M. Gurumurthy, D. V. Ghewade, Shivashankarayya Hiremath and Nithesh Naik
J. Compos. Sci. 2025, 9(4), 176; https://doi.org/10.3390/jcs9040176 (registering DOI) - 5 Apr 2025
Viewed by 40
Abstract
This study investigated the enhancement of the mechanical and tribological properties of MWCNT-reinforced bio-based epoxy composites through systematic experiments and analysis. Composites incorporating MWCNTs at varying weight percentages were evaluated for hardness, wear rate, interfacial shear strength, and friction coefficient under diverse load, [...] Read more.
This study investigated the enhancement of the mechanical and tribological properties of MWCNT-reinforced bio-based epoxy composites through systematic experiments and analysis. Composites incorporating MWCNTs at varying weight percentages were evaluated for hardness, wear rate, interfacial shear strength, and friction coefficient under diverse load, sliding speed, and distance conditions. An optimal MWCNT content of 0.3–0.4% resulted in a maximum hardness of 4 GPa and a minimum wear rate of 0.0058 mm3/N·m, demonstrating a substantial improvement over the non-reinforced system. FTIR and XRD analyses confirmed robust interfacial bonding between the MWCNTs and epoxy matrix, while molecular dynamics simulations revealed cohesive energy density and stress distribution profiles. The Taguchi optimization identified the MWCNT weight percentage as the most influential parameter, contributing over 85% to wear rate reduction. Contour plots and correlograms further illustrate the parameter interdependencies, emphasizing the role of MWCNT dispersion in enhancing the composite properties. These findings establish that MWCNT-reinforced bio-based epoxy composites are promising candidates for high-performance and sustainable tribological applications. Full article
(This article belongs to the Special Issue Characterization and Modeling of Composites, 4th Edition)
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20 pages, 24517 KiB  
Article
Investigations of Thin-Walled Glass Fiber Reinforced Plastic Laminates with Sealing Function for Electric Motors
by Jan David Hübsch, Nils Meyer, Daniela Feldten, Christian Mittelstedt and Philipp Berendes
J. Compos. Sci. 2025, 9(4), 175; https://doi.org/10.3390/jcs9040175 - 3 Apr 2025
Viewed by 68
Abstract
This article presents, in detail, design considerations for a thin-walled glass fiber reinforced plastic (GFRP) liner on a fluid-cooled stator lamination of an electric motor. In addition to structural requirements due to the cooling fluid pressure, the GFRP liner needs to guarantee impermeability. [...] Read more.
This article presents, in detail, design considerations for a thin-walled glass fiber reinforced plastic (GFRP) liner on a fluid-cooled stator lamination of an electric motor. In addition to structural requirements due to the cooling fluid pressure, the GFRP liner needs to guarantee impermeability. Analytical considerations deriving from different coefficients of thermal expansion (CTEs) determine the two-layered laminate design. Empirical investigations show two innovative, simple, and, therefore, efficient test setups for the leakage of liquid media through a GFRP liner. The weeping investigations employ two different GFRP systems with four different configurations of interfiber failure (IFF) and, therefore, crack densities. The weeping investigations show that at least one ply in the laminate needs to be flawless regarding IFF cracks in order to guarantee the sealing function. Alternatively, a third sealing layer can be used. Full article
(This article belongs to the Section Composites Applications)
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18 pages, 6813 KiB  
Article
Effects of Matrix Properties on the Interfacial Shear Strength Between Carbon Fiber and Various Thermoplastic Polymers, and Their Influence on the Mechanical Properties of Composites
by Kazuto Tanaka and Ryota Sakakibara
J. Compos. Sci. 2025, 9(4), 174; https://doi.org/10.3390/jcs9040174 - 2 Apr 2025
Viewed by 59
Abstract
Although fiber–matrix interfacial strengths, which affect the mechanical properties of fiber-reinforced plastics (FRPs), are considered to be determined by complex factors, few studies have systematically evaluated the relationship between the matrix properties and the fiber–matrix interfacial shear strength. In this study, the properties [...] Read more.
Although fiber–matrix interfacial strengths, which affect the mechanical properties of fiber-reinforced plastics (FRPs), are considered to be determined by complex factors, few studies have systematically evaluated the relationship between the matrix properties and the fiber–matrix interfacial shear strength. In this study, the properties of various thermoplastics were measured, and the matrix tightening stress that constricts the fiber was simulated using finite element method (FEM) analysis. The relationships between the fiber–matrix interfacial shear strength and the matrix properties were clarified. The mechanical properties of carbon fiber reinforced thermoplastic (CFRTP) laminates were also evaluated, and the relationships between the fiber–matrix interfacial shear strength and the mechanical properties of CFRTP laminates were examined. The fiber–matrix interfacial shear strength showed a positive correlation with the matrix tightening stress tightening the fiber in the radial direction, as well as with matrix density, tensile strength, modulus, and melting temperature, while a negative correlation was found with the coefficient of linear expansion of the matrix. A higher fiber–matrix interfacial shear strength can be achieved by using a matrix with higher density, even without direct evaluation of the fiber–matrix interfacial strength, as the fiber–matrix interfacial shear strength showed a strong positive correlation with matrix density. Furthermore, the mechanical properties of CFRTP laminates were enhanced when matrices with higher fiber–matrix interfacial shear strength were used. Full article
(This article belongs to the Special Issue Carbon Fiber Composites, 4th Edition)
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17 pages, 14026 KiB  
Article
Analysis of the Deformation Mechanisms of Fabrics Based on rCF Staple Fiber Yarns for Thermoset Composite Applications
by Tobias Georg Lang, Mir Mohammad Badrul Hasan, Anwar Abdkader, Chokri Cherif and Thomas Gereke
J. Compos. Sci. 2025, 9(4), 173; https://doi.org/10.3390/jcs9040173 - 2 Apr 2025
Viewed by 65
Abstract
The draping of textile semi-finished products for complex geometries is still prone to errors, e.g., wrinkles, gaps, and fiber undulations, leading to reduced mechanical properties of the composite. Reinforcing textiles made from carbon fiber (CF) rovings (i.e., endless continuous fibers) can be draped [...] Read more.
The draping of textile semi-finished products for complex geometries is still prone to errors, e.g., wrinkles, gaps, and fiber undulations, leading to reduced mechanical properties of the composite. Reinforcing textiles made from carbon fiber (CF) rovings (i.e., endless continuous fibers) can be draped mainly based on their ability to deform under in-plane shearing. However, CF rovings are hardly stretchable in the fiber direction. These limited degrees of freedom make the production of complex shell-shaped geometries from standard CF-roving fabrics challenging. Contrary to continuous rovings, this paper investigates the processing of spun yarns made of recycled carbon fibers (rCFs), which are discontinuous staple fibers with defined lengths. rCFs are obtained from end-of-life composites or production waste, making them a sustainable alternative to virgin carbon fibers in the high-performance components of, e.g., automobiles, boats, or sporting goods. These staple fiber-spun yarns are considerably more stretchable, which is due to the ability of the individual fibers to slide against each other when deformed, resulting in improved formability of fabrics made from rCF yarns, enabling the draping of much more complex structures. This study aims to develop and characterize woven fabrics based on previous studies of rCF yarns for thermoset composites. In order to investigate staple fiber-spun yarns, a previous micro-scale modeling approach is extended. The formability of fabrics made from those rCF yarns is investigated through experimental forming tests and meso-scale simulations. Full article
(This article belongs to the Special Issue Feature Papers in Journal of Composites Science in 2025)
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15 pages, 4473 KiB  
Article
Composite Films Based on Poly(3-hexylthiophene):Perylene Diimide Derivative:Copper Sulfide Nanoparticles Deposited by Matrix Assisted Pulsed Laser Evaporation on Flexible Substrates for Photovoltaic Applications
by Marcela Socol, Nicoleta Preda, Andreea Costas, Gabriela Petre, Andrei Stochioiu, Gianina Popescu-Pelin, Sorina Iftimie, Ana Maria Catargiu, Gabriel Socol and Anca Stanculescu
J. Compos. Sci. 2025, 9(4), 172; https://doi.org/10.3390/jcs9040172 - 1 Apr 2025
Viewed by 47
Abstract
Today, flexible and lightweight electronics are regarded as a viable alternative to conventional rigid and heavy devices in various application fields. In the optoelectronic area, organic semiconductors offer advantages such as high absorption coefficients, low processing temperatures, mechanical flexibility and compatibility with plastic [...] Read more.
Today, flexible and lightweight electronics are regarded as a viable alternative to conventional rigid and heavy devices in various application fields. In the optoelectronic area, organic semiconductors offer advantages such as high absorption coefficients, low processing temperatures, mechanical flexibility and compatibility with plastic substrates, while inorganic nanostructures provide good electronic properties and high thermal stability. Thus, composite films with enhanced properties can be achieved by inserting inorganic nanostructures within organic layers. In this research work, CuS nanoparticles were prepared by wet chemical precipitation and then added to an organic mixture containing poly(3-hexylthiophene) (P3HT) and N,N-bis-(1-dodecyl)perylene-3,4,9,10 tetracarboxylic diimide (AMC14), a chemically synthesized semiconductor, for fabricating hybrid composite films by matrix assisted pulsed laser evaporation (MAPLE) on indium tin oxide/poly(ethylene terephthalate) (ITO/PET) flexible substrates. A comparative assessment of the morphological, compositional, optical and electrical properties of the composite (P3HT:AMC14:CuS) and organic (P3HT:AMC14) layers was performed to evaluate their applicability in the photovoltaic cells. The transmission and emission spectra of the composite films are dominated by the optical features of AMC14, a perylene diimide derivative compound used as acceptor. In the case of devices based on MAPLE deposited composite layer fabricated on ITO/PET substrates, the electrical measurements carried under illumination revealed an improvement in the open circuit voltage parameter emphasizing their potential applications in the flexible device area. Full article
(This article belongs to the Section Polymer Composites)
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16 pages, 8016 KiB  
Article
Structural Insights: In Situ Synthesis of Titanium Carbide by Magnesiothermic Method Using Carbon Nanotubes and Turbostratic Carbon as Carbon Sources
by María Luisa Camacho-Ríos, Guillermo Herrera-Pérez, Luis Carlos Rodriguez-Pacheco, Mariana Lizbeth Luján-Aguilar, Antonio Ramírez-de la Cruz, Nathaly Withney Aguilar-Cisneros, Marco Antonio Ruiz Esparza-Rodriguez, Daniel Lardizabal-Gutierrez, Raúl Pérez-Bustamante and José Antonio Betancourt-Cantera
J. Compos. Sci. 2025, 9(4), 171; https://doi.org/10.3390/jcs9040171 - 31 Mar 2025
Viewed by 87
Abstract
The current work presents the influence of the magnesiothermic synthesis method on titanium carbide (TiC). In this method, powdered titanium precursors and two carbon sources—turbostratic carbon and carbon nanotubes—were employed in proportions of 10 wt.% and 20 wt.%. The refinement of the X-ray [...] Read more.
The current work presents the influence of the magnesiothermic synthesis method on titanium carbide (TiC). In this method, powdered titanium precursors and two carbon sources—turbostratic carbon and carbon nanotubes—were employed in proportions of 10 wt.% and 20 wt.%. The refinement of the X-ray diffraction (XRD) patterns using the Rietveld method for TiC suggests suggested coexistence of two phases, cubic with Fm-3m space group and hexagonal with P3121 space group. In particular, for the sample with 20 wt.% of carbon sources, the XRD refinement revealed that the cubic phase accounted for 94% of the composition, in contrast to a secondary hexagonal phase, Ti6C3.75, which comprised 6%. The influence of carbon on the morphology (particle size and shape) and crystallite size was monitored through bright-field transmission electron microscopy (BF-TEM) imaging and XRD. In samples containing 20 wt.% carbon, a homogeneous morphology in both size (around 11 microns) and shape was observed, along with a reduction in crystallite size (from 22.7 to 17.8 nm). Raman band analysis further revealed vibrational modes indicating that carbon induced disorder in the TiC structure. The magnesiothermic synthesis method developed in this work offers a low-cost approach of interest in the aerospace and automotive industries. Additionally, the study provides significant insights for particles used as additives or reinforcing agents to enhance the mechanical properties of metal matrix composites (MMCs). Full article
(This article belongs to the Section Carbon Composites)
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14 pages, 4439 KiB  
Article
Dual Influence of Li Concentration and Nanoparticle Size in LiCoO2 on the Conductivity and Storage Capacity of Lithium Batteries
by Obaidallah A. Algethami
J. Compos. Sci. 2025, 9(4), 170; https://doi.org/10.3390/jcs9040170 - 31 Mar 2025
Viewed by 51
Abstract
LixCo1−xO2 nanocomposites with molar concentrations x (0.1, 0.3, 0.5, 0.7, 0.9) were prepared using the sol–gel method. The optical and electrical properties were determined using UV-Vis spectrometer. The results obtained indicate that the absorption coefficient increases upon increase [...] Read more.
LixCo1−xO2 nanocomposites with molar concentrations x (0.1, 0.3, 0.5, 0.7, 0.9) were prepared using the sol–gel method. The optical and electrical properties were determined using UV-Vis spectrometer. The results obtained indicate that the absorption coefficient increases upon increase of nanoparticle size, while the energy gap decreases when nanoparticle size increases. The storage capacity reaches its maximum value near resonance at minimum nanoparticle size. This is attributed to the fact that the optical properties, electrical conductivity, and actual electrical permittivity reach their maximum values near the resonance region and increase as the nanoparticle size decreases. The operating voltages at which the storage capacity attains maximum value in the range from 2.3 to 3.5 volts. These operating voltages can be adjusted to achieve the required range by controlling the Li concentrations and the crystallite size of LixCo1−xO2 NPs which directly affect the energy gap and, in turn, influence the operating voltage. The operating voltage can thus be increased by increasing the energy gap, which requires decreasing the nano size and the Li concentration. Full article
(This article belongs to the Section Nanocomposites)
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43 pages, 7222 KiB  
Review
Materials and Energy-Centric Life Cycle Assessment for Drones: A Review
by Ajitanshu Vedrtnam, Harsha Negi and Kishor Kalauni
J. Compos. Sci. 2025, 9(4), 169; https://doi.org/10.3390/jcs9040169 - 30 Mar 2025
Viewed by 122
Abstract
The rapid expansion of drone applications across industries such as defense, healthcare, construction, agriculture, and surveillance has intensified the need for advanced materials that enhance performance while minimizing environmental impact. This review provides a comprehensive analysis of materials used in drone construction, categorizing [...] Read more.
The rapid expansion of drone applications across industries such as defense, healthcare, construction, agriculture, and surveillance has intensified the need for advanced materials that enhance performance while minimizing environmental impact. This review provides a comprehensive analysis of materials used in drone construction, categorizing them based on their application in key components such as frames, propellers, wings, and structural supports. An energy-centric life cycle assessment (LCA) examines the environmental footprint of drone materials, emphasizing energy use, emissions, and recyclability. The review highlights the trade-offs between mechanical performance and environmental impact, identifying materials that optimize structural efficiency while reducing environmental impact. Additionally, emerging sustainable alternatives such as bio-based composites and recycled carbon fibers are explored as potential solutions for next-generation UAV design. By addressing existing research gaps, this study aims to guide the development of environmentally responsible drone manufacturing technologies. The findings offer valuable insights into optimizing drone materials for enhanced environmental efficiency, supporting the transition toward more energy-efficient and eco-friendly UAVs. Full article
(This article belongs to the Section Composites Applications)
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25 pages, 2459 KiB  
Article
Implementation of Composite Materials for an Industrial Vehicle Component: A Design Approach
by Ivan Tomasi, Stefano Grandi and Luigi Solazzi
J. Compos. Sci. 2025, 9(4), 168; https://doi.org/10.3390/jcs9040168 - 29 Mar 2025
Viewed by 75
Abstract
The aim of this research is to define a design approach for implementing composite materials in a component of an industrial vehicle, having weight reduction as the primary goal. Through the schematisation of the problem and analytical analysis, the definition of a new [...] Read more.
The aim of this research is to define a design approach for implementing composite materials in a component of an industrial vehicle, having weight reduction as the primary goal. Through the schematisation of the problem and analytical analysis, the definition of a new geometry, a material and production process, and numerical simulations and experimental studies to test the new solution, an optimization process of the chosen geometry is proposed. After the definition of the process, an applicative example is presented, analysing a front underrun protection device in two different solutions: one made of glass-fibre-reinforced polymer and the other of carbon-fibre-reinforced polymer. An economic comparison has also been conducted between the new configurations and the traditional steel version, showing a weight reduction of approximately 55% for the carbon-fibre-reinforced polymer solution and around 18% for the glass-fibre-reinforced polymer solution. These weight reductions are achievable through a reinvestment that can be amortized in less than five years, thanks to fuel consumption savings. Full article
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23 pages, 3897 KiB  
Article
Enhancing Polylactic Acid/Carbon Fiber-Reinforced Biomedical Composites (PLA/CFRCs) with Multi-Walled Carbon Nanotube (MWCNT) Fillers: A Comparative Study on Reinforcing Techniques
by Juan Antonio Paz-González, Yadira Gochi-Ponce, Carlos Velasco-Santos, Enrique Alcudia-Zacarias, Arturo Zizumbo-López, Balter Trujillo-Navarrete, Oscar Adrián Morales-Contreras and Luis Jesús Villarreal-Gómez
J. Compos. Sci. 2025, 9(4), 167; https://doi.org/10.3390/jcs9040167 - 29 Mar 2025
Viewed by 117
Abstract
The limited mechanical properties of composite materials, including stiffness, strength, and biocompatibility, restrict their effectiveness in biomedical applications. This research enhanced the mechanical properties and biocompatibility of polylactic acid and carbon fiber-reinforced composites (PLA/CFRCs) by incorporating multi-walled carbon nanotube (MWCNT) fillers. The methodology [...] Read more.
The limited mechanical properties of composite materials, including stiffness, strength, and biocompatibility, restrict their effectiveness in biomedical applications. This research enhanced the mechanical properties and biocompatibility of polylactic acid and carbon fiber-reinforced composites (PLA/CFRCs) by incorporating multi-walled carbon nanotube (MWCNT) fillers. The methodology involved synthesizing MWCNTs and integrating them into PLA/CFRC laminates using fusion-blending, dispersion, and interlaminar spray-coating. Raman spectroscopy confirmed the presence of MWCNTs, with characteristic D and G band peaks and an ID/IG of 1.44 ± 0.089. SEM revealed MWCNTs in the PLA/CFRC matrix and allowed size determination, with an outer diameter range of 125–150 nm and a length of 14,407 ± 2869 nm. FTIR identified interactions between the matrix and the MWCNTs, evidenced by band shifts. TGA/DSC analysis showed thermal stability above 338 °C for all composites. The tensile tests revealed that all composites had values greater than 19 GPa for the elastic modulus and 232 MPa for the ultimate strength. Cytotoxicity assays confirmed biocompatibility, and all samples maintained a cell growth rate greater than 80%. This study highlighted the potential of nanotechnology to optimize the mechanical behavior of polymer-based composites, expanding their applicability in biomedical fields. Full article
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16 pages, 12954 KiB  
Article
A Study on the Charging–Discharging Mechanism of All Solid-State Aluminum–Carbon Composite Secondary Batteries
by Jia-Ying Lin, Bo-Ding Wu and Fei-Yi Hung
J. Compos. Sci. 2025, 9(4), 166; https://doi.org/10.3390/jcs9040166 - 29 Mar 2025
Viewed by 146
Abstract
Aluminum solid-state batteries are emerging as one of the most promising energy storage systems, offering advantages such as low cost and high safety. This study adopts a safe and cost-effective approach by alloying and doping the all-solid-state aluminum-ion battery to enhance its electrochemical [...] Read more.
Aluminum solid-state batteries are emerging as one of the most promising energy storage systems, offering advantages such as low cost and high safety. This study adopts a safe and cost-effective approach by alloying and doping the all-solid-state aluminum-ion battery to enhance its electrochemical performance. This research further explores the electrochemical impacts of these modifications on the performance of solid-state aluminum batteries. In this experiment, aluminum-based anodes were deposited onto nickel foil using the thermal evaporation (TE) method. At the same time, the graphite film (GF) cathode material was enriched with sodium (GFN) through a solution-based process. The system was combined with magnesium silicate solid electrolytes to investigate the all-solid-state aluminum-carbon battery′s structural characteristics and charge–discharge mechanisms. The experimental results demonstrate that the aluminum-coated electrode alloying effects and the graphite film modification significantly improve battery performance. The system achieved a maximum specific capacity of approximately 700 mAh g−1, with a cycle life exceeding 100 cycles. Furthermore, the microstructural characteristics and phase structure of the aluminum evaporation film were confirmed. Analysis of ion transport pathways during the charge–discharge cycles of the all-solid-state aluminum-carbon battery revealed that both aluminum and magnesium ions play critical roles in the electrode processes. Full article
(This article belongs to the Special Issue Feature Papers in Journal of Composites Science in 2025)
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9 pages, 439 KiB  
Article
Effect of Adhesive System on Bond Strength of Polyetheretherketone (PEEK) and Polyetherketoneketone (PEKK)
by Thais Marques Simek Vega Gonçalves, Isabela Reginaldo, Kusai Baroudi, Zuíla Maria Lobato Wanghon, Pedro Santos Diamantino, Mariana Gadelho Gimenez, Analucia Gebler Phillippi, Guilherme de Siqueira Ferreira Anzaloni Saavedra, Fernando Cabral and João Paulo Mendes Tribst
J. Compos. Sci. 2025, 9(4), 165; https://doi.org/10.3390/jcs9040165 - 29 Mar 2025
Viewed by 139
Abstract
It is uncertain whether the interchangeable use of two adhesive systems would yield comparable shear bond strength (SBS) for both Polyetheretherketone (PEEK) and Polyetherketoneketone (PEKK); investigating this was the main objective of this study. Milled PEEK (Bredent, Senden, Germany) and PEKK (Pekkton Ivory, [...] Read more.
It is uncertain whether the interchangeable use of two adhesive systems would yield comparable shear bond strength (SBS) for both Polyetheretherketone (PEEK) and Polyetherketoneketone (PEKK); investigating this was the main objective of this study. Milled PEEK (Bredent, Senden, Germany) and PEKK (Pekkton Ivory, AnaxDent, Stuttgart, Germany) blocks were prepared with standardized roughness (0.20 μm) and randomly assigned into two groups (n = 72): with and without aluminum oxide air abrasion (AquaCare Twin, Medivance Instruments, London, UK). Two adhesive systems (Visio.link, Bredent, Senden, Germany, or PEKKBond, AnaxDent, Stuttgart, Germany) were randomly applied (n = 36). Flowable gingival composite (AnaxGum Gingiva, AnaxDent, Stuttgart, Germany) was bonded, and the samples were stored in water (37 °C, 24 h). SBS was measured (MPa) and data were analyzed using three-way ANOVA, followed by Tukey’s test (α = 0.05). All main effects and interactions were significant (p < 0.05), except for polymer (p = 0.163) and the triple interaction (p = 0.601). In the PEEK group, Visiolink showed higher SBS (p < 0.001), regardless of prior air abrasion. For the PEKK group, PEKKBond significantly increased SBS values (p < 0.001) for both pre-treatment groups. Previous air abrasion only significantly increased the SBS of controls without adhesive. This study highlights the importance of material-specific adhesive selection, rather than interchangeable use, for optimal results. The bond strength of PEEK and PEKK is influenced by the adhesive system applied. Moreover, PEKK consistently demonstrated higher SBS values in comparison to PEEK, even without the need for pre-treatment or adhesive conditioning. This characteristic renders PEKK a preferred choice for the fabrication of adhesive restorations. Full article
(This article belongs to the Special Issue Recent Progress in Hybrid Composites)
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18 pages, 8893 KiB  
Article
Optimization of Innovative Hybrid Polylactic Acid+ and Glass Fiber Composites: Mechanical, Physical, and Thermal Evaluation of Woven Glass Fiber Reinforcement in Fused Filament Fabrication 3D Printing
by Ardi Jati Nugroho Putro, Galang Bagaskara, Ibnu Adnan Prasetya, Jamasri, Ardi Wiranata, Yi-Chieh Wu and Muhammad Akhsin Muflikhun
J. Compos. Sci. 2025, 9(4), 164; https://doi.org/10.3390/jcs9040164 - 29 Mar 2025
Viewed by 203
Abstract
The growing demand for complex structures, energy absorption, and mechanically strong materials has led to the exploration of innovative composites. This study focuses on the manufacture, characterization, and evaluation of PLA+ reinforced with woven glass fiber. Using Fused Filament Fabrication (FFF) 3D Printer [...] Read more.
The growing demand for complex structures, energy absorption, and mechanically strong materials has led to the exploration of innovative composites. This study focuses on the manufacture, characterization, and evaluation of PLA+ reinforced with woven glass fiber. Using Fused Filament Fabrication (FFF) 3D Printer technology, the effects of adding woven glass fiber were examined through a tensile test with Digital Image Correlation (DIC)-induced, flexural, Charpy impact resistance, Shore D hardness, Differential Scanning Calorimetry (DSC) thermal tester, and SEM morphological tests. Results showed that adding four layers of glass fiber significantly improved mechanical properties: tensile strength increased by 85% to 95.44 MPa, flexural strength by 13% to 91.51 MPa, and impact resistance by 450% to 15.12 kJ/m2. However, a reduction in hardness and thermal resistance was noted due to chemical interactions. These findings suggest potential applications of PLA+ composites in high-strength products for vehicle bumpers in the automotive industry and shin pads in the sports industry. Full article
(This article belongs to the Special Issue Recent Progress in Hybrid Composites)
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16 pages, 6626 KiB  
Article
Effect of Monomer Composition on the Core–Shell Structure and Expansion Performance of Thermally Expandable Microspheres
by Deli Yang, Yanxiang Wang, Yanqiu Feng, Haotian Jiang, Yongbo Wang, Shichao Dai, Bohan Ding, Yue Sun and Jinghe Guo
J. Compos. Sci. 2025, 9(4), 163; https://doi.org/10.3390/jcs9040163 - 28 Mar 2025
Viewed by 177
Abstract
This study investigated the effect of different monomer compositions of acrylonitrile (AN) and methyl methacrylate (MMA) on the synthesis and expansion performance of thermally expandable microspheres (TEMs). TEMs with different monomer ratios, specifically AN to MMA ratios of 100:0, 90:10, 80:20, and 70:30, [...] Read more.
This study investigated the effect of different monomer compositions of acrylonitrile (AN) and methyl methacrylate (MMA) on the synthesis and expansion performance of thermally expandable microspheres (TEMs). TEMs with different monomer ratios, specifically AN to MMA ratios of 100:0, 90:10, 80:20, and 70:30, were synthesized via free radical suspension polymerization. The inner morphology, crystallinity, blowing agent encapsulation efficiency, and expansion ratio of the microspheres were analyzed using scanning electron microscopy (SEM), Fourier-transform infrared spectroscopy (FTIR), thermogravimetric analysis (TGA), and other characterization techniques. The results showed that as the MMA content and reaction time increased, the internal structure of the microsphere shell became more uniform, and its thickness increased. Notably, the P(AN:MMA)(90:10) microspheres exhibited the lowest expansion temperature and the highest expansion ratio. This study provides a theoretical basis for the further optimization of TEM synthesis processes. Full article
(This article belongs to the Special Issue Recent Progress in Hybrid Composites)
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