Search Results (1,490)

The frequent introduction and rapid spread of invasive alien species (IAS) along with the limited resources available for their management highlight the need to adopt simple and effective methods for prioritizing management efforts. Here, we propose a technically simple model for prioritizing management actions, using Sicily (southern Italy) as a case study. Despite its invasion being relatively recent and the species not yet widespread, the highly invasive red swamp crayfish Procambarus clarkii proved to be able to colonize different habitat types on this Mediterranean island. We adopted a multicriteria analysis method based on geographic information systems (GIS) to identify both the vulnerability of different areas to its invasion, the likelihood of their invasion, and the impact that the occurrence of the red swamp crayfish might have on habitats or species of conservation relevance. The data used in our analysis are routinely available to local administrations and can be easily processed to map the most vulnerable areas for biodiversity protection. The simplicity of the model makes it particularly suitable for local administrative bodies to plan and implement effective invasive species management interventions, optimizing time and costs and allowing the development of concrete nature conservation actions. Full article

Atmospheric water harvesting (AWH) is a promising alternative to address immediate water needs. Desiccant-based AWH could compete effectively with other commercially available AWH technologies. One of the primary challenges facing desiccant-based AWH is the energy required to desorb the captured water vapor from the desiccant. This work presents a multi-faceted approach targeted explicitly at low-humidity and arid regions, aiming to overcome the limitations of the refrigerant-based AWH system. It includes assessing common desiccants (zeolite, activated alumina, and silica gel) and their forms (beads, powdered, or coated on a substrate). A bench-scale test rig was designed to evaluate different types and forms of desiccants for adsorption and desorption cycles and overall adsorption capacity (g/g), kinetic profiles, and rates. Experimental results indicate that beaded desiccants possess the highest adsorption capacity compared to powdered or coated forms. Furthermore, coated desiccants double the water uptake (1.12 vs. 0.56 g water/g desiccant) and improve adsorption/desorption cycling by 52% compared to beaded forms under the same conditions. Additionally, Brunauer–Emmett–Teller (BET), X-ray diffraction (XRD), and dynamic vapor sorption (DVS) analysis show the pore geometry, morphology, and sorption capacity. The goal is to integrate these performance improvements and propose a more effective, energy-efficient desiccant-based AWH system. Full article

The worldwide adoption of artificial turf in sports facilities and urban landscapes, alongside the systematic transition from natural grass and soil-based grounds, has raised growing concerns about its contribution to the significant source of nano- and microplastics in ecosystems. This review examines current knowledge on the mechanisms of nano- and microplastic generation from artificial turf systems and their environmental impacts. Combined mechanical stress, ultra-violet radiation, and weathering processes contribute to the breakdown of synthetic grass fibers and infill materials, generating particles ranging from nanometer to millimeter scales. These nano- and microplastics are detected in drainage systems and surrounding soils near sports facilities. Laboratory studies demonstrate that artificial turf-derived nano- and microplastics can adversely affect soil microbial communities, aquatic organisms, and potentially human health, through various exposure pathways. While current mitigation approaches include hybrid turf, particle retention systems, and improved maintenance protocols, emerging research focuses on developing novel, environmentally friendly materials as alternatives to conventional synthetic turf components. However, field data on emission rates and environmental fate remain limited, and standardized methods for particle characterization and quantification are lacking. This review identifies critical knowledge gaps, underscoring the need for comprehensive research on long-term ecological impacts and highlights the future goal of mitigating nano- and microplastic emissions from artificial turf systems into the ecosystem. Full article

Per- and polyfluoroalkyl substances (PFASs) are a class of manufactured organic chemicals that are widely employed for their heat-, oil-, and water-resistant properties. Studies have shown that the bioaccumulation of PFASs in living organisms and their related health effects are sufficient for classifying them as a group of toxicants worthy of great concern and further study. While PFASs travel through the air and soil, their contamination of water pathways proves to be the most common route for exposure. We analyzed PFASs from three different wastewater treatment plants (WWTPs) throughout Arizona to show that, despite treatment efforts, they persist as contaminants in water sources. Using U.S. Environmental Protection Agency method 1633, seasonally obtained field samples were prepared for analysis through liquid chromatography–tandem mass spectrometry. A total of 24 samples were taken at different stages of the treatment process to assess the proficiency of the removal processes during remediation. Duplicate samples were each taken from Tucson’s WWTP and Flagstaff’s WWTP before and after chlorination, and from three sites in Yuma County, upstream effluent, downstream effluent, and WWTP, before chlorination. From the samples obtained in Yuma, perfluorooctanesulfonic acid, perfluorooctanoic acid, and perfluorohexanesulfonic acid were detected but at levels below their limits of quantification. PFBS was detected at the Yuma and Tucson WWTP at levels up to 4.52 ng/L and 73.53 ng/L, respectively. The samples obtained from Flagstaff’s WWTP were below the instrument level of detection and, therefore, characterized as non-detects. Full article

Highly contaminated waste from an old mercury mine facility was covered with fly ash from a coal-burning power plant that was analyzing the rainwater infiltration in a full-scale test in which the influencing variables were monitored for a year. A sufficiently low hydraulic conductivity and sufficiently high porosity of the ash, and the relationship between evapotranspiration and precipitation were the most important factors controlling rainwater infiltration through the fly ash layer to produce contaminated leachate. A fly ash layer with a thickness between 10 and 50 cm, depending on climatic conditions, works as a barrier to partially or totally prevent, depending on the scenario considered, rainwater contamination. Overall, the solution proposed in this study results in economic savings in all the cases considered, because treatments for eliminating PTEs from waste are usually expensive. On the other hand, the effect is permanent over time, as it is based on a physical barrier effect, while the contamination reduction is independent of the initial concentration and the contamination reduction is for any PTE (Hg, Pb, Zn, etc.). Full article

Renewable natural gas derived from biogas presents a viable pathway for decarbonizing natural gas systems. Wastewater treatment plants equipped with anaerobic digesters often flare or utilize biogas for heat and electricity generation, missing the potential of renewable natural gas. This study investigates the techno-economic feasibility and emission impact of a renewable natural gas system at a small wastewater treatment plant in the Southwestern United States. Due to a lack of existing data on biogas composition and contaminants from plants originating within the United States, samples were tested seasonally for a year, and gas components are reported in this analysis. Using hourly biogas production data, the analysis incorporates costs and renewable fuel credits at 2022 market prices and the cost to remove the biogas contaminants. The results show a 15-year net present value of USD 16.3 million, with a payback period of three years, surpassing the economic performance of combined heat and power systems previously assessed for the same facility. Additionally, renewable natural gas systems achieve a 22% reduction in site emissions compared to combined heat and power systems. These findings highlight renewable natural gas as a profitable and environmentally superior alternative for biogas utilization in small-scale wastewater treatment plants, contingent on access to renewable fuel credits. Full article

Pollution in mining areas represents a major environmental issue, significantly impacting ecosystems and human health. This study highlights propolis as an efficient natural bioindicator for detecting and assessing the degree of contamination in these areas. The objective of this study is to determine the levels of metals (Pb, Cd, As, Cr, Fe, Mn, Cu, and Zn) in propolis from mining exploitation areas in Romania, specifically in the counties of Alba, Hunedoara, Maramureș, and Caraș-Severin. Although mining operations are closed, the anthropogenic impact varies due to differences in the surface areas of the zones affected, the areas occupied by waste heaps, local hydrological conditions, and partial ecological rehabilitation efforts. To highlight the impact of contamination, a reference area considered unaffected by anthropogenic activities was used as a benchmark for each county. The values obtained in the investigated area were compared with those from this control zone to determine the differences and the specific impact of pollution. Maximum values were recorded in Roșia Montană for Pb (9.27 mg·kg⁻¹), Cd (0.17 mg·kg⁻¹), and As (0.87 mg·kg⁻¹); in Băile Borșa for Fe (150.23 mg·kg⁻¹) and Zn (2.9 mg·kg⁻¹); in Certeju de Sus for Cu (6 mg·kg⁻¹) and Cr (7.01 mg·kg⁻¹); and in Moldova Nouă for Mn (25.43 mg·kg⁻¹). The maximum content values of phenols (189.49 mg·kg⁻¹ in Alba County) and flavonoids (88.06 mg·kg⁻¹ in Caraș-Severin) were recorded, as well as the minimum IC₅₀ antioxidant activity (0.33 µg·mL⁻¹). Propolis from these areas showed antimicrobial activity against five bacterial strains (Staphylococcus aureus, Escherichia coli, Pseudomonas aeruginosa, Enterococcus faecalis, and Streptococcus mutans) and five fungal strains (Candida albicans, Aspergillus niger, Aspergillus flavus, Cryptococcus neoformans, and Penicillium chrysogenum), although such antimicrobial and antifungal activities were more intense in unpolluted areas. The present study reveals that propolis is a natural indicator of heavy metal pollution in mining areas. These data support the usefulness of propolis due to its high capacity to accumulate and reflect environmental contaminants. Full article

This review analyzes the relationship between Urban Heat Island (UHI) microclimate parameters and poor air quality in urban environments, focusing on how temperature variations, wind dynamics, and urban morphology influence pollutant concentrations. Experimental studies and numerical simulations emphasize the necessity of pedestrian-level sensing combined with computational fluid dynamics (CFD) simulations to accurately capture spatial variations in UHI-related parameters. Ozone concentrations have been observed to increase by up to 4 ppbv, while PM_2.5 levels rise by 1–2 µg/m³ in response to UHI effects. Additionally, ANSYS Fluent 2020.R1. simulations demonstrate a 0.93 °C error in temperature predictions and a 1.35 m/s error in wind speed estimations. These findings highlight the critical role of sustainable urban planning strategies in mitigating UHI effects and improving air quality in densely populated areas. Full article

The Chickahominy T.R.U.T.H. (Trust, Research, Understand, Teach, and Heal) Project investigates water quality concerns, including potential contamination from a nearby landfill, and their corresponding health implications among residents of rural Charles City County, Virginia. This rural, majority-racial-minority county includes citizens of the Chickahominy Indian tribe. The T.R.U.T.H. Project utilizes a community-based participatory research approach and environmental justice-focused lens to study water quality and health; the present study represents the first comprehensive analysis of the drinking water quality of homes with domestic groundwater wells. We collected water samples from 121 participants located within a four-mile radius of the landfill, analyzing over 200 potential analytes that may affect water quality. Among the measured analytes, water pH, aluminum, iron, manganese, and hardness as CaCO₃ were most frequently identified as having ratings outside of established EPA limits (“Bad”). Logistic regression models demonstrated that proximity to streams near the landfill was associated with significantly greater odds of worse water quality for several analytes. Specifically, residing within a mile of these streams was associated with greater odds of “Fair” or worse turbidity (OR = 4.31, 95% CI 1.31–19.53) and zinc levels (OR = 2.63, 95% CI 1.23–5.86). Additionally, residing within half a mile of a proximate stream was linked with “Poor” or worse hardness ratings (OR = 10.71, 95% CI 1.64–86.96); residing within a mile of the landfill was associated with “Bad” water pH levels (OR = 10.50, 95% CI 1.16–95.68). Though many tested analytes did not have concerning ratings or were not significantly associated with proximity to the landfill or streams, the above findings suggest that anthropogenic factors, particularly landfill proximity, may influence water quality with regard to specific analytes. Therefore, addressing water quality through enhanced monitoring, contaminant remediation, and community education is crucial for restoring trust in drinking water and improving public health outcomes. Full article

Although the circular economy (CE) has emerged as an innovative approach to address the challenges of protecting natural resources, the use of its strategies remains in its infancy, particularly in West Africa. This study examines the factors influencing the use of CE strategies in the wood and forestry sector in Benin. This study relied on a methodological approach based on surveys, using interview guides to collect information in both the southern and northern zones of the country. This information was collected at the level of the different actors directly involved in this sector, to identify the factors that influence the use of CE strategies using Probit models. The results show that access to information, the number of years of professional experience, the age of the actors and the type of training received are the determining factors in the use of these strategies (the models statistically significant at the 1% level). Other factors, such as knowledge of the costs and benefits of different strategies, are also identified as fundamental. Furthermore, a high financial capacity and an excess or overload of information are identified as the limiting factors for the use of these strategies. Full article

Concerns over pharmaceutical contaminants are increasing due to their high biological activity and ubiquity, with wastewater being the main source. Ibuprofen is extensively used worldwide and commonly detected in freshwaters due to its low degradability during wastewater treatment. Daphnia magna is the most-used model taxon for toxicity testing of ibuprofen, but this crustacean is known to be less sensitive to some contaminants than several freshwater insect groups. Our study assessed the toxicity of ibuprofen (nominal concentration range 2.0–2147.5 µg/L) to a native New Zealand mayfly, Deleatidium spp., in a 7-day static renewal experiment, with the neonicotinoid imidacloprid (1.4 µg/L) as a reference toxicant. Test concentrations of ibuprofen included three field-realistic and four higher concentrations that might occur in severely polluted streams. Mayfly responses indicated some negative trends (decreased survival and moulting propensity, increased impairment and immobility), but all patterns were non-significant. The imidacloprid control also had no significant impacts but tended to increase mayfly impairment. Overall, Deleatidium nymphs were largely unaffected by the entire range of experimental ibuprofen concentrations, suggesting that ibuprofen may be a relatively benign stressor for these organisms, although longer-term exposure experiments are needed to confirm if they demonstrate susceptibility to chronic exposure. Full article

Environmental contamination is ubiquitous and even in the ocean, signs of contamination of different types (chemical, biological, or plastic) are detected in all kinds of environments. In this study, a sediment core was sampled at the bottom of the Blue Hole of the Maldives (Ari Atoll) to make a first characterization of the sediment in terms of its grain size and organic–inorganic matter composition and to assess the sediment contamination levels in terms of trace elements (by ICP-MS analysis) and the eventual presence of microplastics (by optical classification and microRaman analysis of items). High concentrations of Hg (a maximum value of 0.145 ppm at the bottom layer of the core), Cd (a maximum value of 0.65 ppm at the core surface layer), and As (9.4 ppm at the top of the core) were highlighted at different layers of the sediment core. Plastic polymers were not detected in the sediment core, but 51 fibers characterized by the presence of artificial dyes or additives were found in the core (a mean of 5.7 fibers for each slice). The results confirmed the sediment contamination of the Maldivian Blue Hole, supporting the hypothesis of contamination due to ineffective waste management within the archipelago and mass tourism affecting the atolls. Full article

Manganese (Mn) is widely used in many industries but is also biologically harmful when abundant in the environment. While there are several commercially available methods for manganese removal from water, efficient and cost-effective solutions for addressing manganese contamination in diverse environmental matrices remain limited. In this study, we developed a new method for removing Mn from contaminated lakes using an aptamer. The Seo-Gok Reservoir was selected as the study area due to its significant levels of Mn contamination. We first screened aptamers that bind to Mn through systematic evolution of ligands by exponential enrichment (SELEX). Among 6 aptamers (from FA-M1 to FA-M6), the FA-M1 aptamer exhibited the highest binding affinity to Mn with the lowest Kd value of 4.56 × 10⁻⁹ M. Potential Mn-binding sites in aptamers were predicted by analyzing the secondary structures. To confirm the binding of Mn to the proposed region, we evaluated the sequence homology of the screened aptamers. Aptamer specificity was evaluated against diverse metals. We demonstrated that FA-M1 could remove more than 95% of Mn from an aqueous sample; 99.9% of this Mn could then be recovered. FA-M1 removed more than 90% of Mn from a sample of the Mn-contaminated Seo-Gok Reservoir, indicating that aptamers can be utilized to remove Mn ions from the environment. Full article

The Amazon has undergone significant changes in the landscape with the expansion of human activities. The objective of this study was to characterize the relationship between soil temperature (ST) and moisture (SM) with meteorological data and soil attributes in pasture, forest, and transition areas in the Itacaiúnas River Watershed (IRW), Eastern Amazon. Soil samples were analyzed to determine chemical and granulometric attributes. SM and ST were measured up to 40 cm deep using sensors, and the meteorological variables were quantified by hydrometeorological stations. The chemical characteristics and granulometry indicated greater limitations in the Forest soil, with lower levels of organic carbon and higher contents of sand. In Pasture A, Pasture B, and Transition areas, with some exceptions, there was a progressive increase in ST from July to September. In general, SM was positively correlated with rainfall and negatively correlated with ST, air temperature, wind speed, and solar radiation. Linear models for ST (10–20 cm depth) in Pasture B and Forest areas indicate positive relationships with air temperature and wind speed and negative relationships with solar radiation. The findings of this study can be useful in decision-making regarding the management of ecosystems in the IRW. Full article

At present, the amount of heavy metals in some aquifers exceeds the limits established by standards, especially in developing countries. Cadmium is present in high concentrations in aquifers; contact with cadmium can lead to some adverse health effects. Adsorption is one of the most efficient and low-cost methods currently used to separate heavy metals from water systems. In order to obtain a sustainable heavy metal adsorption system, abundant, low-cost, biodegradable, and easy-to-treat organic waste compounds were sought. Three biosorbents were chosen: orange, peanut, and banana peel, which, due to their functional groups, can attract the positive ions of metals and form a bond that allows them to be absorbed and separated from the aqueous solution. The presence of functional groups such as -OH, -CO, -COO⁻, and -N-H were found to be the main responsible for biosorption (FTIR). Square wave voltammetry was used to analyze the amount of cadmium in an aqueous solution. It was found that the systems with the best adsorption capacities were untreated peanut peel (284.2 mg/g), untreated orange peel (275.5 mg/g), and treated banana peel (229.21 mg/g). Treatment of the peels for cadmium uptake is not recommended. Full article